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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 6
BKCSDE 27(6)
June 20, 2006 

Vibronic Emission Spectrum of Jet-Cooled o-Tolunitrile in a Corona Excited Supersonic Expansion
Chan Ho Park, Gi Woo Lee, Sang Kuk Lee*
Spectroscopy, Vibrational mode, o-Tolunitrile
We have employed a technique of corona excited supersonic expansion to generate electronically excited but jet-cooled o-tolunitrile. The vibronically well-resolved emission spectrum of the jet-cooled o-tolunitrile in the S1 → S0 transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. The electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined from the analysis of the spectra observed.
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