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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 26, Number 10
BKCSDE 26(10)
October 20, 2005

Title	Selective Hydrogenation of 1,3-Butadiene over Supported Nickel Catalyst Obtained from Nickel-Zirconia Solid Solution
Author	Jong-San Chang, Jae Oak Ryu, Jong Min Lee, Sang-Eon Park, Do-Young Hong, Sung Hwa Jhung
Keywords	Ni-ZrO₂, Solid solution, Selective hydrogenation
Abstract	Catalytic properties of Ni-ZrO₂ catalysts prepared by coprecipitation have been studied for the gas-phase hydrogenation of 1,3-butadiene to butenes. The coprecipitation method led to the solid solution of Ni-ZrO₂, which contains highly resistant Ni species to thermal reduction with H₂. Nickel species of the solid solution were highly dispersed in the ZrO₂ lattice, so that the reduced catalysts were selective for hydrogenation of 1,3- butadiene to butenes (99.9%) even in the presence of 1-butene.
Page	1512 - 1514
Full Text	PDF

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