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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 26, Number 9
BKCSDE 26(9)
September 20, 2005

Title	Fuctionalization of SBA-16 Mesoporous Materials with Cobalt(III) Cage Amine Complex
Author	Sang-Cheol Han, Sujandi, Sang-Eon Park*
Keywords	SBA-16, Grafting, Cobalt, Diaminosarcophagine, Confinement effect
Abstract	Surface modification of tridimensional cubic mesoporous silica, SBA-16, was investigated with pendant arm functionalized cobalt diaminosarcophagine (diAMsar) cage complex which covalently grafted onto the silica surface through the silication with sylanol group. The spectroscopic results showed that the mesoporous structure was preserved under the [Co(diAMsar)]³⁺ grafting reaction condition. Successful grafting prevented the cobalt diAMsar cage from leaching out from the SBA-16 support.
Page	1381 - 0
Full Text	PDF

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