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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 25, Number 9
BKCSDE 25(9)
September 20, 2004 
 
Title
 A Convenient Synthesis of Optically Active Unhindered Aliphatic Alcohols with High Optical Purity from Non-Racemic β-Hydroxy Sulfides
Author
 Byung Tae Cho*, Dong Jun Kim
Keywords
 Chiral aliphatic alcohols, Asymmetric reduction, (S)-CBS oxazaborolidine, Chiral β-hydroxy sulfides
Abstract
 A general route for the synthesis of optically active unhindered aliphatic alcohols, where the steric demands between two alkyl groups adjacent to the carbinol are similar, with high enantiomeric purity has been developed by sulfoxifation of chiral β-hydroxy sulfides, followed by alkylation and desulfurization.
Page
 1385 - 1391
Full Text
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