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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 24, Number 7
BKCSDE 24(7)
July 20, 2003

Title	NMR Solvent Peak Suppression by Piecewise Polynomial Truncated Singular Value Decomposition Methods
Author	Daesung Kim, Hyekyoung Lee, Youngdo Won, Dai-Gyoung Kim, Youngwoo Lee, Hoshik Won
Keywords	Nuclear magnetic resonance, Piecewise polynomial truncated singular value decomposition method, Peak suppression
Abstract	A new modified singular value decomposition method, piecewise polynomial truncated SVD (PPTSVD), which was originally developed to identify discontinuity of the earth’s radial density function, has been used for large solvent peak suppression and noise elimination in nuclear magnetic resonance (NMR) signal processing. PPTSVD consists of two algorithms of truncated SVD (TSVD) and L1 problems. In TSVD, some unwanted large solvent peaks and noise are suppressed with a certain soft threshold value, whereas signal and noise in raw data are resolved and eliminated in L1 problems. These two algorithms were systematically programmed to produce high quality of NMR spectra, including a better solvent peak suppression with good spectral line shapes and better noise suppression with a higher signal to noise ratio value up to 27% spectral enhancement, which is applicable to multidimensional NMR data processing.
Page	967 - 970
Full Text	PDF

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