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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 24, Number 1
BKCSDE 24(1)
January 20, 2003 

Reactivity of [Pt(dppf)Cl2] toward Simple Organic Thiolates: Preparation and Structures of [Pt(dppf)(SPh)2], [Pt(dppf)(S-n-Pr)2], and [Pt(dppf)(SCH2CH2CH2S)] (dppf = Fe( h5-C5H4PPh2)2)
Won Seok Han, Yong-Joo Kim, Soon W. Lee
Platinum, dppf, Organic thiolates, X-ray, Cyclovoltammograms
The reactions of [Pt(dppf)Cl2] with thiophenol (PhSH), 1-propanethiol (n-PrSH), and 1,3-propanedithiol (HSCH2CH2CH2SH) gave the corresponding Pt-dppf-di(thiolato) compounds, [Pt(dppf)(SPh)2] (1), [Pt(dppf)(S-n-Pr)2] (2), and [Pt(dppf)(SCH2CH2CH2S)] (3), respectively. All products are monomeric and 4- coordinate square-planar compounds and were structurally characterized by X-ray diffraction. Electrochemical measurements (cyclovoltammograms) revealed that the oxidation potential of the dppf ligand appears to depend on the type of the group on the thiolato ligand.
60 - 64
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