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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 22, Number 2
BKCSDE 22(2)
February 20, 2001 

Widths and Positions of Isolated Resonances in the Predissociation of SH: Quantal Treatments
Sungyul Lee, Hosung Sun
Resonance, Predissociation, SH.
The predissociating resonances are treated for the SH molecule by quantal method. The isolated resonances (N'=0, v' = 0-6) are predicted to be highly Lorentzian. The widths and positions of the isolated resonances are computed as functions of v'. The magnitudes and signs of the widths and the shifts as functions of v' are discussed in terms of the distance of the resonance from the crossing points between the bound state (A 2Σ+ ) and the repulsive states ( 4Σ- , 2Σ- and 4Π).
210 - 212
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