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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 21, Number 2
BKCSDE 21(2)
February 20, 2000 

Development of Synthitic Self-assembling Molecular Capsule: from Flexible Spacer to Rigid Spacer
Jongimin Kang, Robert S. Meissner, Rene Wyler, Javier de Mendoza, Julius Rebek Jr
The synthesis and characterization of a synthetic self-assembling molecular capsule are described. The originally designed flexible molecule 1 was collapsing on itself, forming hydrogen bonds within monomer rather than forming a dimer due to the flexibility of the central diimide. A more rigid system 23 was designed and synthesized. The preorganization of this molecule for dimerization led the system self-assembling molecular capsule successfully.
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