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Liquid-Liquid Equilibrium and Physical Properties of Aqueous Mixtures of Poly (Ethylene Glycol) 3000 with Tri-Potassium Citrate at Different pH: Experiment, Correlation and Thermodynamic Modeling


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TableS1.

Density, ρ, and Refractive Index, nD, for the binary and ternary of PEG 3000 (p) + tri-potassium citrate (s) + water system at 298.15 Ka and 0.1 MPab at various mass fractions of polymer, wp and salt, ws

w p c w s c ρ( ± 0.0001) k g m 3 nD (±0.0001)
0.00 0.00 0.9970 1.3327
0.05 0.00 1.0057 1.3394
0.10 0.00 1.0120 1.3458
0.20 0.00 1.0297 1.3599
0.30 0.00 1.0475 1.3743
0.00 0.02 1.0097 1.3357
0.00 0.06 1.0349 1.3413
0.00 0.10 1.0603 1.3470
0.00 0.20 1.1278 1.3615
0.00 0.30 1.1999 1.3760
0.05 0.02 1.0177 1.3416
0.07 0.02 1.0209 1.3444
0.1 0.02 1.0259 1.3487
0.15 0.02 1.0343 1.3559
0.05 0.05 1.0364 1.3468
0.10 0.05 1.0445 1.3539
0.15 0.05 1.0686 1.3609
0.05 0.10 1.0683 1.3540
0.10 0.10 1.0780 1.3612
0.15 0.10 1.0680 1.3683
0.05 0.15 1.1012 1.3615
0.08 0.15 1.1081 1.3658

a298.15 ± 0.05 K, b100 ± 0.05 kPa, c%mass ± 0.001