Liquid-Liquid Equilibrium and Physical Properties of Aqueous Mixtures of Poly (Ethylene Glycol) 3000 with Tri-Potassium Citrate
at Different pH: Experiment, Correlation and Thermodynamic Modeling
TableS1.
Density, ρ, and Refractive Index, nD, for the binary and ternary of PEG 3000 (p) + tri-potassium citrate (s) + water system at 298.15 Ka and 0.1 MPab at various mass fractions of polymer, wp and salt, ws
w
p
c
|
w
s
c
|
ρ(
±
0.0001)
k
g
⋅
m
−
3
|
nD (±0.0001)
|
0.00
|
0.00
|
0.9970
|
1.3327
|
0.05
|
0.00
|
1.0057
|
1.3394
|
0.10
|
0.00
|
1.0120
|
1.3458
|
0.20
|
0.00
|
1.0297
|
1.3599
|
0.30
|
0.00
|
1.0475
|
1.3743
|
0.00
|
0.02
|
1.0097
|
1.3357
|
0.00
|
0.06
|
1.0349
|
1.3413
|
0.00
|
0.10
|
1.0603
|
1.3470
|
0.00
|
0.20
|
1.1278
|
1.3615
|
0.00
|
0.30
|
1.1999
|
1.3760
|
0.05
|
0.02
|
1.0177
|
1.3416
|
0.07
|
0.02
|
1.0209
|
1.3444
|
0.1
|
0.02
|
1.0259
|
1.3487
|
0.15
|
0.02
|
1.0343
|
1.3559
|
0.05
|
0.05
|
1.0364
|
1.3468
|
0.10
|
0.05
|
1.0445
|
1.3539
|
0.15
|
0.05
|
1.0686
|
1.3609
|
0.05
|
0.10
|
1.0683
|
1.3540
|
0.10
|
0.10
|
1.0780
|
1.3612
|
0.15
|
0.10
|
1.0680
|
1.3683
|
0.05
|
0.15
|
1.1012
|
1.3615
|
0.08
|
0.15
|
1.1081
|
1.3658
|